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The "Physical Chemistry" textbook by McQuarrie in PDF format is an excellent resource for:

: It uses the molecular properties derived from quantum mechanics to build up macroscopic properties. Classical Thermodynamics physical chemistry mcquarrie pdf

To understand the demand for the PDF, one must first understand the product. Published in 1997 (with a second edition in 2007 co-authored with John D. Simon), McQuarrie’s Physical Chemistry represented a paradigm shift in how the subject was taught. The "Physical Chemistry" textbook by McQuarrie in PDF